This study investigates the impact of ground granulate blast-furnace slag (GGBFS) and fly ash (FA) on both the corrosion resistance of steel reinforcement, assessed through the accelerated macrocell corrosion test (AMCT), and the durability characteristics of highperformance concrete (HPC). Additionally, the study encompasses an analysis of various concrete properties, including the pH of fresh concrete mixtures as well as water absorption, chloride permeability, and surface resistivity (SR) in hardened concrete specimens. Microstructure analysis on HPC specimens as well as the service life prediction of RCS were also performed in this study. Test results show that the HPC incorporating 35% GGBFS or 35% GGBFS + 20% FA as cement replacement resulted in a lowered pH of fresh mixtures while water absorption and chloride permeability of these specimens increased significantly. In addition, the incorporation of 35% GGBFS or 35% GGBFS + 20% FA concurrently enhanced the SR of HPC specimens. Moreover, these HPC specimens exhibited better corrosion resistance ability as their respective AMCT values were about 1.54 and 1.45 times higher than that of the control specimen. Further, the research highlighted a substantial extension in the corrosion initiation time of concrete structures employing 35% GGBFS or 35% GGBFS + 20% FA, about 3 and 6 times longer than the HPC without GGBFA and FA, respectively. The experimental results, confirmed by the substantial microstructural enhancement in the HPC containing GGBFS and FA, also demonstrated a close interplay between durability and other concrete properties such as water absorption, chloride permeability, and SR.