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Bài báo - Tạp chí
5 (2020) Trang: 1374-1396
Tạp chí: Reaction Chemistry & Engineering

To enhance crop efficiency and meet the growing global demands for food, a new agri-tech revolution has recently been triggering. Engineered nanomaterials have potential of lessening environmental impact and making agriculture more efficient, resilient, and sustainable. Nitrogen-doped nanoparticles (N-doped NPs) are a rising star toward development of new generation of nanopesticides for advanced green agriculture providing improved efficiency, new concepts for pest control and reduced pesticide resistance, which are key limitation of conventional pesticides. The objectives of this paper are (1) to provide perspectives of promising applications of N-doped NPs as emerging nanopesticides and (2) to review the opportunities which plasma-enabled NP technology for the scalable production of N-doped NPs based on a green and eco-friendly and sustainable approach. Main advantages of the N-doped NPs are their multifunctionality enabling to provide enhanced adhesion on leaves or insect bodies and several different modes of action to kill insects including physics, biochemical and catalytic that are expected to considerably reduce insects. Apart from insects, these nanomaterials can inactivate phytopathogenic bacteria and fungi throughout various mechanisms and therefore used for a broad spectrum of plant protection. In this review, N-doped ZnO and N-doped TiO2 NPs will be introduced and reviewed as the first examples of these nanomaterials that have been successfully proven as nanopesticides. Following the first demonstration and the application of N-doped carbon dots (N-doped CDs) various, agricultural applications such as nanopesticides, pesticide nanocarriers, disease detection, and pest targeting will be reviewed showing their enormous potential to be translated into real applications. The plasma technology comes into play when the focus is on the manufacturing process of these nanomaterials, since, in pest control, producing high-quality nanopesticides is indispensable and challenging. Plasma-chemical NP processing is a green, simple, and rapid approach, compared to conventional methods and this review presents how this technology can be used to produce N-doped NPs in high quality, high quantity, low-cost and sustainable way with minimal waste, energy efficiency and without of the use of toxic chemicals. The implementation of this technology and introduction Ndoped NPs as new powerful pesticidal agents could make significant impact in improved crop production

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